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51.
Raolin Huang Prof. Dr. Frederic W. Patureau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(70):e202202135
A facile and environmentally friendly electrochemical protocol is herein reported for the C(sp2)−C(sp3) cross dehydrogenative coupling between imidazopyridines and N,N-dimethylanilines. The broad functional group compatibility includes halogens, ester, alcohol, sulfone as well as thiophene. This methodology is also suitable for benzo[d]imidazo[2,1-b]thiazole, thiazoimidazole and tetrahydroisoquinoline, and can be scaled up to 5 mmol. Mechanistic insights are discussed. 相似文献
52.
通过解析和数值的方法研究了二维微裂纹体有效模量和有效导电系数之间的关联,针对二维含有任意取向和平行的微裂纹介质,通过基于象素的有限元方法分别计算了它们的有效杨氏模量和有效导电系数,并建立了两种不同物理量之间的关联.研究结果表明利用简单的解析Mori-Tanaka方法也可以建立上述关联,并且与数值结果吻合很好。 相似文献
53.
S. D. Algazin 《Journal of Applied Mechanics and Technical Physics》2006,47(4):573-581
The problem of free vibrations of a beam with free ends of variable cross section and mass, from which point masses (oscillators)
are suspended by bars, is considered. It is shown that parametric resonances can occur in this oscillating system. Numerical
examples showing the efficiency of the calculation method proposed are given.
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Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 4, pp. 135–144, July–August, 2006. 相似文献
54.
本文研究单阶和多阶截面杆在集中和分布轴向荷载作用下的弹性稳定计算方法,首次给出了其整体稳定和局部稳定的解析解. 相似文献
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Elastic electron scattering with formamide-(H2O)n complexes (n=1, 2): Influence of microsolvation on the π* and σ* resonances 下载免费PDF全文
Kedong Wang 《中国物理 B》2021,30(12):123401-123401
We report elastic cross sections for low-energy electron scattering with formamide-(H2O)n complexes (n=1, 2) in the energy region of 0.01-8 eV. The scattering calculations are performed using the R-matrix method in the static-exchange (SE) approximation. We consider three structures of formamide-H2O and six structures of formamide-(H2O)2 in the present work. Our purpose is to investigate effects of water molecules hydrogen-bonding to formamide. We focus on the influence of microsolvation on the π* and σ* resonances of formamide. The scattering result for complexes shows that the position of π* resonance appears at lower or higher energies in the cluster than in the isolated formamide depending on the complex structure and the water role in the hydrogen bonding. We explain this behavior according to the net charge of the solute. It is found that the microsolvation environment has a substantial effect on the width of π* resonance. Our results indicate that surrounding water molecules may affect the lifetime of the resonances, and hence the process is driven by the anion state, such as the dissociative electron attachment. 相似文献
58.
Elastic scattering angular distributions and total reaction cross-sections of ~(7,10,11,12)Be projectiles are predicted by the systematic ~9 Be global phenomenological optical model potential for target mass numbers ranging from24 to 209. These predictions provide a detailed analysis by their comparison with the available experimental data.Furthermore, these elastic scattering observables are also predicted for some targets out of the mass number range.The results are in reasonable agreement with the existing experimental data, and they are presented in this study. 相似文献
59.
Rama Moorhy Appa S. Siva Prasad Jangam Lakshmidevi Bandameeda Ramesh Naidu Manchala Narasimhulu Katta Venkateswarlu 《应用有机金属化学》2019,33(10)
An agro waste‐derived, ‘water extract of pomegranate ash’ (WEPA), has been utilized for the first time as a renewable medium for Pd(OAc)2‐catalysed Suzuki–Miyaura cross‐coupling at room temperature. This method offers a simple and sustainable synthesis of biaryls from aryl halides and arylboronic acids under ligand‐ and external base‐free aerobic and ambient conditions. This method has been found effective for both activated and unactivated aryl halides in the production of biaryls with moderate to nearly quantitative yields. The protocol shows high chemoselectivity over identical/similar reactive sites in aryl halides (i.e. selectivity over identical halogens or different halogens of aryl halides). This method exhibits high regioselectivity, i.e. the selective reactivity of a halogen over other identical halogens at different positions on the aromatic nucleus. Therefore, we disclose here a clean, benign, substantial chemo‐ and regioselective and highly economic alternative method for the palladium‐assisted synthesis of biaryls using an agro waste‐derived medium. 相似文献
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